Multicenter electron-sharing σ-bonding in the AgFe(CO)4− complex-Reference-Cited by-同舟云学术

Multicenter electron-sharing σ-bonding in the AgFe(CO)4− complex

Published:2020 Issue:43 Volume:49 Page:15256-15266
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Liu Zhiling¹²³⁴⁵^ORCID,Bai Yan¹²³⁴⁵,Li Ya¹²³⁴⁵,He Jing¹²³⁴⁵,Lin Qingyang¹²³⁴⁵,Hou Lina¹²³⁴⁵,Wu Hai-Shun¹²³⁴⁵,Zhang Fuqiang¹²³⁴⁵,Jia Jianfeng¹²³⁴⁵^ORCID,Xie Hua⁶⁷⁸⁹¹⁰,Tang Zichao¹¹¹²¹³¹⁴¹⁵

Affiliation:

1. School of Chemical and Material Science

2. Key Laboratory of Magnetic Molecules & Magnetic Information Materials

3. the Ministry of Education

4. Shanxi Normal University

5. Linfen

6. State Key Laboratory of Molecular Reaction Dynamics

7. Dalian Institute of Chemical Physics

8. Chinese Academy of Sciences

9. Dalian 116023

10. China

11. Collaborative Innovation Center of Chemistry for Energy Materials

12. State Key Laboratory for Physical Chemistry of Solid Surfaces

13. and Department of Chemistry

14. College of Chemistry and Chemical Engineering

15. Xiamen University

Abstract

For the AgFe(CO)₄⁻ anion, the silver atom is covalently bonded to the anionic tetracarbonyl-iron, an isolobal analogue of the methyl radical, via a peculiar decentralized electron-sharing σ bond.

Funder

Shanxi Normal University

National Natural Science Foundation of China

Shanxi Province Science Foundation for Youths

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2020/DT/D0DT02685A

Reference95 articles.

1. XCIII.—On iron carbonyls