Unusual {⋯HNC2O⋯HCnO}, n = 1 or 2, synthons predominate in the molecular packing of one-dimensional coordination polymers, {Cd[S2P(OR)2]2(3LH2)}n, for R = Me and Et, but are precluded when R = i-Pr; 3LH2 = N,N′-bis(3-pyridylmethyl)oxalamide-Reference-Cited by-同舟云学术

Unusual {⋯HNC₂O⋯HC_nO}, n = 1 or 2, synthons predominate in the molecular packing of one-dimensional coordination polymers, {Cd[S₂P(OR)₂]₂(³LH₂)}_n, for R = Me and Et, but are precluded when R = i-Pr; ³LH₂ = N,N′-bis(3-pyridylmethyl)oxalamide

Published:2022 Issue:16 Volume:24 Page:2992-3004
ISSN:1466-8033
Container-title:CrystEngComm
language:en
Short-container-title:CrystEngComm

Author:

Tan Yee Seng¹^ORCID,Yeo Chien Ing¹^ORCID,Kwong Huey Chong¹^ORCID,Tiekink Edward R. T.¹^ORCID

Affiliation:

1. Research Centre for Crystalline Materials, School of Medical and Life Sciences, Sunway University, 47500 Bandar Sunway, Selangor Darul Ehsan, Malaysia

Abstract

The electronic & steric influence of the dithiophosphate-R groups mediates the formation of unprecedented supramolecular synthons.

Funder

Sunway University

Publisher

Royal Society of Chemistry (RSC)

Subject

Condensed Matter Physics,General Materials Science,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/CE/D2CE00208F

Reference47 articles.

1. Solid-State Structures of Hydrogen-Bonded Tapes Based on Cyclic Secondary Diamides

2. Hierarchy of Supramolecular Synthons: Persistent Carboxylic Acid···Pyridine Hydrogen Bonds in Cocrystals That also Contain a Hydroxyl Moiety

3. Coordination polymers, metal–organic frameworks and the need for terminology guidelines

4. E. R. T.Tiekink , Crystal chemistry of the isomeric N,N'-bis(pyridin-n-ylmethyl)-ethanediamides, n = 2, 3 or 4, in Multi-Component Crystals. Synthesis, Concepts, Function , ed. E. R. T. Tiekink and J. Zukerman-Schpector , De Gruyter , Singapore , 2017

5. Controlled Spacing of Metal Atoms via Ligand Hydrogen Bonds