Trimacrocyclic hexasubstituted benzene linked by labile octahedral [X(CHCl3)6]− clusters-Reference-Cited by-同舟云学术

Trimacrocyclic hexasubstituted benzene linked by labile octahedral [X(CHCl3)6]− clusters

Published:2021 Issue:35 Volume:12 Page:11647-11651
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Lai Zhenzhen¹,Li Aimin¹,Peng Sangshan¹^ORCID,Sessler Jonathan L.²^ORCID,He Qing¹^ORCID

Affiliation:

1. State Key Laboratory of Chemo/Biosensing and Chemometrics, College of Chemistry and Chemical Engineering, Hunan University, Changsha 410082, P. R. China

2. Department of Chemistry, The University of Texas at Austin, 105 East 24th Street, Stop A5300, Austin, Texas 78712, USA

Abstract

We report the synthesis and robust crystallization of a trimacrocyclic hexasubstituted benzene and guanidium mediated by unprecedented labile halide hexasolvate clusters, viz. [Cl(CHCl3)6]−, [Br(CHCl3)6]−, [I(CHCl3)6]−, and [Br(CHBr3)6]−.

Funder

National Natural Science Foundation of China

Welch Foundation

Science and Technology Program of Hunan Province

Fundamental Research Funds for the Central Universities

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/SC/D1SC03713G

Reference35 articles.