A novel samarium(ii) complex bearing a dianionic bis(phenolate) cyclam ligand: synthesis, structure and electron-transfer reactions-Reference-Cited by-同舟云学术

A novel samarium(ii) complex bearing a dianionic bis(phenolate) cyclam ligand: synthesis, structure and electron-transfer reactions

Published:2016 Issue:9 Volume:45 Page:3778-3790
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Maria Leonor¹²³⁴⁵,Soares Marina¹²³⁴⁵,Santos Isabel C.¹²³⁴⁵,Sousa Vânia R.¹²³⁴⁵,Mora Elsa¹²³⁴⁵,Marçalo Joaquim¹²³⁴⁵,Luzyanin Konstantin V.⁶⁷⁸⁹¹⁰

Affiliation:

1. Centro de Ciências e Tecnologias Nucleares

2. Instituto Superior Técnico

3. Universidade de Lisboa

4. 2695-066 Bobadela LRS

5. Portugal

6. Institute of Chemistry

7. Saint Petersburg State University

8. 198504 Saint Petersburg

9. Russian Federation

10. Department of Chemistry

Abstract

A novel divalent samarium complex anchored on a dianionic bis(phenolate) ligand is reported and reactivity studies demonstrate that it is highly effective in inducing single-electron transfer processes.

Funder

Russian Foundation for Basic Research

Fundação para a Ciência e a Tecnologia

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/DT/C5DT04647E

Reference56 articles.

1. Twenty-five years of organic chemistry with diiodosamarium: an overview

2. Recent advances in the chemoselective reduction of functional groups mediated by samarium(ii) iodide: a single electron transfer approach

3. Synthesis and x-ray crystal structure of a soluble divalent organosamarium complex

4. Solution synthesis and crystallographic characterization of the divalent organosamarium complexes (C5Me5)2Sm(THF)2 and [(C5Me5)Sm(.mu.-I)(THF)2]2

5. Synthesis and crystallographic characterization of an unsolvated, monomeric samarium bis(pentamethylcyclopentadienyl) organolanthanide complex, (C5Me5)2Sm

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