Metal ion clip: fine-tuning aromatic stacking interactions in the multistep formation of carbazole-bridged zinc(ii) complexes-Reference-Cited by-同舟云学术

Metal ion clip: fine-tuning aromatic stacking interactions in the multistep formation of carbazole-bridged zinc(ii) complexes

Published:2015 Issue:50 Volume:51 Page:10103-10106
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Imai Yuki¹²³⁴,Kawai Tsuyoshi¹²³⁴,Yuasa Junpei¹²³⁴⁵

Affiliation:

1. Graduate School of Materials Science

2. Nara Institute of Science and Technology

3. 8916-5 Takayama

4. Japan

5. PRESTO

Abstract

A carbazole-based triple bridging ligand (LH) consisting of two imidazole moieties with a diketone unit forms carbazole-bridged zinc(ii) complexes with structures of [(L⁻)₄(Zn²⁺)_n] (n = 2–6), where the strength of aromatic stacking interactions between the carbazole rings increases with an increase in the number of Zn²⁺ ions bridged.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2015/CC/C5CC03281D

Reference25 articles.

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