Reversible polypeptide hydrogels from asymmetric telechelics with temperature-dependent and Ni2+-dependent connectors
Author:
Affiliation:
1. Physical Chemistry and Soft Matter
2. Wageningen University
3. 6703 HB Wageningen, The Netherlands
Abstract
An asymmetric (‘hybrid’) triblock polypeptide TR4H with two different, orthogonally self-assembling end blocks has been constructed by conjugating a long (37 kDa) random coil block (R4) with a triple helix former T = (Pro-Gly-Pro)9 at the N terminus, and a histidine hexamer (‘Histag’, H) at the C terminus.
Publisher
Royal Society of Chemistry (RSC)
Subject
Condensed Matter Physics,General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2016/SM/C6SM00218H
Reference28 articles.
1. Multiresponsive Reversible Gels Based on Charge-Driven Assembly
2. The influence of charge ratio on transient networks of polyelectrolyte complex micelles
3. Effect of Self-Assembly on Probe Diffusion in Solutions and Networks of pH-Sensitive Triblock Copolymers
4. Temperature/pH Responsive Hydrogels Based on Poly(ethylene glycol) and Functionalized Poly(e-caprolactone) Block Copolymers for Controlled Delivery of Macromolecules
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