Preparation of intrinsically fragile bent crystals

Author:

Seki Tomohiro1ORCID,Kobayashi Shiori1,Ishikawa Rintaro1,Yano Keigo2,Matsuo Takumi23ORCID,Hayashi Shotaro23ORCID

Affiliation:

1. Department of Chemistry, Faculty of Science, Shizuoka University, Shizuoka City, Shizuoka 422-8017, Japan

2. School of Engineering Science, Kochi University of Technology, 185 Miyanokuchi, Tosayamada, Kami, Kochi 782-8502, Japan

3. Research Institute, Kochi University of Technology, 185 Miyanokuchi, Tosayamada, Kami, Kochi 782-8502, Japan

Abstract

A methylated flufenamic acid gave two different polymorphs, mechanically deformable α form and fragile γ form. We successfully obtained the “intrinsically brittle” bent γ crystal by vapor-induced phase transition from the bent α crystal.

Funder

Japan Society for the Promotion of Science

Fusion Oriented REsearch for disruptive Science and Technology

Japan Science and Technology Agency

Publisher

Royal Society of Chemistry (RSC)

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