Polymerization of phenylacetylenes by binuclear rhodium catalysts with different para-binucleating phenoxyiminato linkages

Author:

Wu Xiaolu12345,Zhang Pengfei12345,Yang Zhi12345,Zhang Shaowen12345,Liu Hao12345,Chi Weijie12345,Li Xiaofang12345ORCID,Dong Yuping67385ORCID,Qiu Nannan91045,Yan Li11385

Affiliation:

1. Key Laboratory of Cluster Science of Ministry of Education

2. School of Chemistry and Chemical Engineering

3. Beijing Institute of Technology

4. Beijing

5. China

6. Beijing Key Laboratory of Construction Tailorable Advanced Functional Materials and Green Applications

7. School of Materials Science and Engineering

8. Beijing 100081

9. NHC Key Laboratory of Food Safety Risk Assessment

10. China National Centre for Food Safety Risk Assessment

11. Analytical and Testing Center

Abstract

A binuclear rhodium catalyst 3b with a 2,5-phenyloxydiiminato linkage and an nbd ligand exhibits cooperative effects in terms of enhanced catalytic activity in the polymerization of phenylacetylene and its functional derivatives.

Funder

National Natural Science Foundation of China

Higher Education Discipline Innovation Project

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Polymers and Plastics,Biochemistry,Bioengineering

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