Iron(iii) bis(pyrazol-1-yl)acetate based decanuclear metallacycles: synthesis, structure, magnetic properties and DFT calculations

Author:

Gajewska Małgorzata J.1234,Bieńko Alina5678,Herchel Radovan910111213ORCID,Haukka Matti141516,Jerzykiewicz Maria5678,Ożarowski Andrzej17181920,Drabent Krzysztof5678,Hung Chen-Hsiung1234

Affiliation:

1. Institute of Chemistry

2. Academia Sinica

3. Taipei 105

4. Taiwan

5. Faculty of Chemistry

6. Wrocław University

7. 50-383 Wrocław

8. Poland

9. Regional Centre of Advanced Technologies and Materials & Department of Inorganic Chemistry

10. Faculty of Science

11. Palacký University

12. 771 46 Olomouc

13. Czech Republic

14. Department of Chemistry

15. FI-40014 University of Jyväskylä

16. Finland

17. National High Magnetic Field Laboratory

18. Florida State University

19. Tallahassee

20. USA

Abstract

A new member of the decanuclear ferric wheel family with the formula [Fe10(bdtbpza)102-OCH3)20], featuring the N,N,O tridentate bis(3,5-di-tert-butylpyrazol-1-yl)acetate ligand, is reported.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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