The curious case of a sterically crowded Stenhouse salt-Reference-Cited by-同舟云学术

The curious case of a sterically crowded Stenhouse salt

Published:2022 Issue:33 Volume:13 Page:9755-9760
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Théry Valentin¹,Molton Florian¹,Sirach Selim¹,Tillet Neven¹,Pécaut Jacques²,Tomás-Mendivil Eder¹,Martin David¹^ORCID

Affiliation:

1. Univ. Grenoble Alpes, CNRS, DCM, Grenoble 38000, France

2. Univ. Grenoble Alpes, CEA, CNRS, INAC-SyMMES, UMR 5819, Grenoble 38000, France

Abstract

Bulky substituents of a Stenhouse salt prevent the usual formation of a cyclopentenone upon deprotonation. For the first time, a transient open-chain neutral derivative was observed; the cyclized form and an air-persistent radical were isolated.

Funder

H2020 Marie Skłodowska-Curie Actions

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/SC/D2SC01895K

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