The effect of σ/π, σ and π donors on the basicity of silylene superbases: a density functional theory study-Reference-Cited by-同舟云学术

The effect of σ/π, σ and π donors on the basicity of silylene superbases: a density functional theory study

Published:2018 Issue:13 Volume:42 Page:11153-11159
ISSN:1144-0546
Container-title:New Journal of Chemistry
language:en
Short-container-title:New J. Chem.

Author:

Biswas Abul Kalam¹²³⁴⁵,Si Mrinal Kanti¹²³⁴⁵,Ganguly Bishwajit¹²³⁴⁵^ORCID

Affiliation:

1. Analytical Discipline and Centralized Instrument Facility

2. Academy of Scientific and Innovative Research

3. CSIR–Central Salt & Marine Chemicals Research Institute

4. Bhavnagar

5. India

Abstract

In this study, we examined computationally that the combination of π-and σ-donor substituents results in higher basicity of silylene compounds compared to the usage of π-donor substituents alone.

Funder

University Grants Commission

Council of Scientific and Industrial Research

Department of Biotechnology, Ministry of Science and Technology

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2018/NJ/C8NJ00263K

Reference66 articles.

1. Synthesis and Structure of a Stable Silylene

2. Zwitterionic and Donor-Stabilized N-Heterocyclic Silylenes (NHSis) for Metal-Free Activation of Small Molecules

3. Lewis Base Stabilized Dichlorosilylene

4. New insights into small molecule activation by acyclic silylenes: a computational investigation

5. Soluble Allotropes of Main-Group Elements

Cited by 5 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Strong Bases Design: Key Techniques and Stability Issues;International Journal of Molecular Sciences;2024-08-09

2. Strong Bases Design: Predicted Limits of Basicity;The Journal of Physical Chemistry A;2022-06-03

3. The formation of H···X hydrogen bond, C···X carbon-halide or Si···X tetrel bonds on the silylene-halogen dimers (X = F or Cl): intermolecular strength, molecular orbital interactions and prediction of covalency;Theoretical Chemistry Accounts;2020-07-15

4. Utilizing the Azaazulene Scaffolds in the Design of New Organic Superbases;ACS Omega;2019-09-04

5. Novel silicon super bases at DFT level of theory: effects of fused benzene rings on the basicity of 2,4,6-cycloheptatrienesilylene;Research on Chemical Intermediates;2019-05-29