Isolable arene sandwiched copper(i) pyrazolates
Author:
Affiliation:
1. Department of Chemistry and Biochemistry
2. The University of Texas at Arlington
3. Arlington
4. USA
5. Department of Chemistry
6. Faculty of Science
7. University of Peradeniya
8. Peradeniya
9. Sri Lanka
Abstract
The π-acidic, trinuclear, copper(i) pyrazolate {[3,5-(CF3)2Pz]Cu}3 reacts with simple π-basic aromatic hydrocarbon compounds forming sandwich complexes of various types.
Publisher
Royal Society of Chemistry (RSC)
Subject
Materials Chemistry,General Chemistry,Catalysis
Link
http://pubs.rsc.org/en/content/articlepdf/2015/NJ/C5NJ01002K
Reference27 articles.
1. Metal Azolate Frameworks: From Crystal Engineering to Functional Materials
2. Brightly Phosphorescent Trinuclear Copper(I) Complexes of Pyrazolates: Substituent Effects on the Supramolecular Structure and Photophysics
3. Trinuclear Copper(I) and Silver(I) Adducts of 4-Chloro-3,5-bis(trifluoromethyl)pyrazolate and 4-Bromo-3,5-bis(trifluoromethyl)pyrazolate
4. Structure of tris(.mu.-3,5-diphenylpyrazolato-N,N')tricopper(I). Structural comparisons with the silver(I) and gold(I) pyrazolate trimers
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