Spin-glass behavior of a hierarchically-organized, hybrid microporous material, based on an extended framework of octanuclear iron-oxo units-Reference-Cited by-同舟云学术

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Spin-glass behavior of a hierarchically-organized, hybrid microporous material, based on an extended framework of octanuclear iron-oxo units

Published:2015 Issue:7 Volume:44 Page:3399-3409
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Cao Xin-Yi¹²³⁴,Hubbard Jeremiah W.⁵⁶⁷⁴,Guerrero-Medina Jennifer⁵⁶⁷⁴,Hernández-Maldonado Arturo J.⁵⁶⁷⁴^ORCID,Mathivathanan Logesh¹²³⁴,Rinaldi Carlos⁵⁶⁷⁴,Sanakis Yiannis⁸⁹¹⁰¹¹,Raptis Raphael G.¹²³⁴

Affiliation:

1. Department of Chemistry and Institute for Functional Nanomaterials

2. University of Puerto Rico

3. San Juan

4. USA

5. Department of Chemical Engineering

6. University of Puerto Rico-Mayagüez Campus

7. Mayagüez

8. Institute of Materials Science

9. NCSR “Demokritos”

10. Athens

11. Greece

Abstract

An amorphous microporous solid, hierarchically built using paramagnetic octanuclear iron-oxide clusters, becomes a spin-glass below ∼30 K.

Funder

National Science Foundation

National Aeronautics and Space Administration

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/DT/C4DT02606C

Reference87 articles.

1. Long-Range Ordered Carbon Clusters: A Crystalline Material with Amorphous Building Blocks

2. Amorphous Molecular Organic Solids for Gas Adsorption

3. Facile Mechanosynthesis of Amorphous Zeolitic Imidazolate Frameworks

4. Bringing Order to Amorphous Silicon

5. Deconstructing the Crystal Structures of Metal–Organic Frameworks and Related Materials into Their Underlying Nets

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2. Molecular Clusters: Nanoscale Building Blocks for Solid-State Materials;Accounts of Chemical Research;2018-03-31

3. Structures and applications of metal–organic frameworks featuring metal clusters;CrystEngComm;2017

4. Chemical reaction within a compact non-porous crystal containing molecular clusters without the loss of crystallinity;Chemical Science;2017

5. Drastic Deprotonation Reactivity Difference of 3- and 5-Alkylpyrazole Isomers, Their I2-Catalyzed Thermal Isomerization, and Telescoping Synthesis of 3,5-Dialkylpyrazoles: The “Adjacent Lone Pair Effect” Demystified;The Journal of Organic Chemistry;2016-02-03

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