How does the combination of the nitro group and fluorine atoms affect the (co)crystallization behaviour of arylenediamines?

Author:

Vaganova Tamara A.1ORCID,Gatilov Yurij V.1,Kryuchkova Natalia A.2,Pishchur Denis P.2ORCID,Zhukovets Anastasia A.1ORCID,Malykhin Evgenij V.1ORCID

Affiliation:

1. Siberian Branch of the Russian Academy of Sciences, N.N. Vorozhtsov Novosibirsk Institute of Organic Chemistry, 9 Lavrentiev Avenue, 630090 Novosibirsk, Russian Federation

2. Siberian Branch of the Russian Academy of Sciences, Nikolaev Institute of Inorganic Chemistry, 3 Lavrentiev Avenue, 630090 Novosibirsk, Russian Federation

Abstract

Fluorine substituents control the stoichiometry and supramolecular structure of co-crystals affecting the electron density distribution over the molecule and, thus, the strength of H-bonds and p⋯π electron interactions.

Funder

Ministry of Science and Higher Education of the Russian Federation

Publisher

Royal Society of Chemistry (RSC)

Subject

Condensed Matter Physics,General Materials Science,General Chemistry

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