A new method for detecting intramolecular H-bonds of aromatic amides based on the de-shielding effect of carbonyl groups on β-protons-Reference-Cited by-同舟云学术

A new method for detecting intramolecular H-bonds of aromatic amides based on the de-shielding effect of carbonyl groups on β-protons

Published:2021 Issue:23 Volume:23 Page:13284-13291
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Min Jing¹²³⁴⁵,Wang Chunyu¹²³⁴⁵^ORCID,Wang Liyan¹²³⁴⁵^ORCID

Affiliation:

1. State Key Laboratory of Supramolecular Structure and Materials

2. College of Chemistry

3. Jilin University

4. Changchun 130012

5. China

Abstract

We develop a Δ(δ_βH) method to detect intramolecular hydrogen bonds in aromatic amide compounds, which is based on the fact that the de-shielding effect of carbonyl groups on β-hydrogen is enhanced due to the restricted intramolecular rotation.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2021/CP/D1CP01089A

Reference43 articles.

1. Foldamers: A Manifesto

2. Supramolecular Single-Chain Polymeric Nanoparticles

3. Self‐assembly of Amphiphilic Alternating Copolymers

4. Aromatic Oligoamide Foldamers

5. Aromatic Amide Foldamers: Structures, Properties, and Functions

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