Effects of carbonate on ferrihydrite transformation in alkaline media

Author:

Li Ying12ORCID,Zhang Chaoqun3,Yang Meijun3,Liu Jing4,He Hongping3,Ma Yibing1,Arai Yuji2

Affiliation:

1. National Observation and Research Station of Coastal Ecological Environments in Macao, Macao Environmental Research Institute, Faculty of Innovation Engineering, Macau University of Science and Technology, Macao SAR 999078, China

2. Department of Natural Resources and Environmental Sciences, University of Illinois at Urbana-Champaign, Urbana, IL 61801, USA

3. CAS Key Laboratory of Mineralogy and Metallogeny/Guangdong Provincial Key Laboratory of Mineral Physics and Materials, Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, Guangzhou 510640, China

4. State Key Laboratory of Lunar and Planetary Sciences, Macau University of Science and Technology, Taipa, 999078, Macau, China

Abstract

This study indicates that in alkaline media, carbonate slightly inhibits ferrihydrite transformation and suppresses goethite formation, but promotes hematite formation, which has important implications for elemental biogeochemical cycles.

Funder

U.S. Department of Agriculture

Macau University of Science and Technology

Fundo para o Desenvolvimento das Ciências e da Tecnologia

Publisher

Royal Society of Chemistry (RSC)

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