Growth of membranes formed by associating polymers at interfaces

Author:

Govorun Elena N.1ORCID,de Baubigny Julien Dupré2,Perrin Patrick2,Reyssat Mathilde1ORCID,Pantoustier Nadège2,Salez Thomas3ORCID,Monteux Cécile2ORCID

Affiliation:

1. UMR CNRS Gulliver 7083, ESPCI Paris, PSL Research University, 75005 Paris, France

2. Sciences et Ingénierie de La Matière Molle, UMR 7615, ESPCI Paris, PSL Research University, CNRS, Sorbonne Universités, 75005 Paris, France

3. Université Bordeaux, CNRS, LOMA, UMR 5798, 33405 Talence, France

Abstract

Membrane film growth at weak PMAA ionization is described as a process controlled by interdiffusion. The slowdown at higher ionization can be explained by a drop in the film composition gradient and an electrostatic barrier at the film boundaries.

Funder

Agence Nationale de la Recherche

Publisher

Royal Society of Chemistry (RSC)

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