Selective Buchwald–Hartwig arylation of <i>C</i>-amino-1,2,4-triazoles and other coordinating aminoheterocycles enabled by bulky NHC ligands and TPEDO activator-Reference-Cited by-同舟云学术

Selective Buchwald–Hartwig arylation of C-amino-1,2,4-triazoles and other coordinating aminoheterocycles enabled by bulky NHC ligands and TPEDO activator

Published:2023 Issue:1 Volume:10 Page:218-239
ISSN:2052-1553
Container-title:Inorganic Chemistry Frontiers
language:en
Short-container-title:Inorg. Chem. Front.

Author:

Astakhov Alexander V.¹^ORCID,Chernenko Andrey Yu.¹,Kutyrev Vadim V.¹,Ranny Gleb S.¹,Minyaev Mikhail E.²^ORCID,Chernyshev Victor M.¹^ORCID,Ananikov Valentine P.¹²^ORCID

Affiliation:

1. Platov South-Russian State Polytechnic University, (NPI), Prosvescheniya st., 132, Novocherkassk, 346428, Russia

2. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Leninsky Prospect 47, Moscow, 119991, Russia

Abstract

A facile method for selective N-(hetero)arylation of coordinating 3(5)-amino-1,2,4-triazoles under Pd/NHC catalysis using TPEDO as a new efficient Pd(ii) to Pd(0) reductant has been developed.

Funder

Russian Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/QI/D2QI01832B

Reference121 articles.

1. Applications of Palladium-Catalyzed C–N Cross-Coupling Reactions

2. Buchwald-Hartwig reaction: An overview

3. The Buchwald–Hartwig Amination After 25 Years