Highly dispersed, ultra-small and noble metal-free Cu nanodots supported on porous SiO2 and their excellent catalytic hydrogenation of dimethyl oxalate to methyl glycolate
Author:
Affiliation:
1. State Key Laboratory of Coal Conversion
2. Institute of Coal Chemistry
3. Chinese Academy of Sciences
4. Taiyuan
5. China
Abstract
Noble metal-free ultra-small and highly dispersed Cu/SiO2 catalyst with high Cu+/(Cu+ + Cu0) ratio synthesized by novel and rapid sonochemical method displayed excellent MG selectivity.
Funder
National Natural Science Foundation of China
Chinese Academy of Sciences
Publisher
Royal Society of Chemistry (RSC)
Subject
Materials Chemistry,General Chemistry,Catalysis
Link
http://pubs.rsc.org/en/content/articlepdf/2018/NJ/C8NJ01627E
Reference33 articles.
1. Hydrogenation of Dimethyl Oxalate over Copper-Based Catalysts: Acid–Base Properties and Reaction Paths
2. Structure evolution of mesoporous silica supported copper catalyst for dimethyl oxalate hydrogenation
3. High-performance Ag-CuOx nanocomposite catalyst galvanically deposited onto a Ni-foam for gas-phase dimethyl oxalate hydrogenation to methyl glycolate
4. Enhanced chemoselective hydrogenation of dimethyl oxalate to methyl glycolate over bimetallic Ag–Ni/SBA-15 catalysts
5. Silver nanoparticles confined in carbon nanotubes: on the understanding of the confinement effect and promotional catalysis for the selective hydrogenation of dimethyl oxalate
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