Utilizing a needle as a source of iron in synergistic dual photoredox catalytic generation of alkoxy radicals-Reference-Cited by-同舟云学术

Utilizing a needle as a source of iron in synergistic dual photoredox catalytic generation of alkoxy radicals

Published:2022 Issue:73 Volume:58 Page:10241-10244
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Ondrejková Alica¹^ORCID,Lindroth Rickard¹,Hilmersson Göran¹,Wallentin Carl-Johan¹^ORCID

Affiliation:

1. Department of Chemistry and Molecular Biology, University of Gothenburg, 412 58 Gothenburg, Sweden

Abstract

An iron catalysed and visible-light mediated alkoxy radical generation is described, which allows for a chemoselective oxidative C(sp3)–H bond functionalization providing access to two sets of structurally divergent functionalities.

Funder

Vetenskapsrådet

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2022/CC/D2CC03262G

Reference28 articles.

1. Alkoxy Radicals See the Light: New Paradigms of Photochemical Synthesis

2. Fragmentation of Carbohydrate Anomeric Alkoxy Radicals: A New Synthesis of Chiral 1-Halo-1-iodo Compounds

3. Fragmentation of Carbohydrate Anomeric Alkoxy Radicals. A New General Method for the Synthesis of Alduronic Acid Lactones

4. Intramolecular β,γ-addition of allylic alkoxyl radicals. A new general synthesis of α-iodoepoxides by photolysis of allylic alcohol hypoiodites in the presence of mercury(II) oxide, iodine and pyridine in benzene

5. Oxidation of organic compounds with cerium(IV). VII. Formation constants for 1:1 cerium(IV)-alcohol complexes

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