Formation of a dimeric tungsten(i) complex via C–H activation
Author:
Affiliation:
1. Department of Basic Sciences
2. Preparatory Year Deanship
3. King Faisal University
4. 31982 Al-Hassa
5. Saudi Arabia
6. Lehrstuhl Anorganische Chemie II
7. Universität Bayreuth
8. 95440 Bayreuth
9. Germany
Abstract
The first example of the reactivity of an M2(0) core with π-donating ligands is reported. A quadruply bonded W2(0) complex upon reaction with a cryptand undergoes an intramolecular C–H bond activation of the supporting ligand to form a W2(i) complex.
Funder
Deanship of Scientific Research, King Faisal University
Deutsche Forschungsgemeinschaft
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2020/DT/C9DT04847B
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