Formation of a dimeric tungsten(i) complex via C–H activation
Author:
Affiliation:
1. Department of Basic Sciences
2. Preparatory Year Deanship
3. King Faisal University
4. 31982 Al-Hassa
5. Saudi Arabia
6. Lehrstuhl Anorganische Chemie II
7. Universität Bayreuth
8. 95440 Bayreuth
9. Germany
Abstract
The first example of the reactivity of an M2(0) core with π-donating ligands is reported. A quadruply bonded W2(0) complex upon reaction with a cryptand undergoes an intramolecular C–H bond activation of the supporting ligand to form a W2(i) complex.
Funder
Deanship of Scientific Research, King Faisal University
Deutsche Forschungsgemeinschaft
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2020/DT/C9DT04847B
Reference54 articles.
1. Ultrashort metal–metal distances and extreme bond orders
2. Discovering complexes containing a metal–metal quintuple bond: from theory to practice
3. Theory, synthesis and reactivity of quintuple bonded complexes
4. M5M – Key compounds of the research field metal–metal quintuple bonding
Cited by 6 articles. 订阅此论文施引文献 订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献
1. The Synthesis and Structure of Scandium Dichloride of Sterically Demanding Aminopyridinato Ligands;Molbank;2024-04-10
2. Syntheses and structural characterization of tris- and tetrakis(aminopyridinate) complexes of lanthanum;Inorganica Chimica Acta;2024-01
3. Aminopyridinato ligand complexes—Precursors for nanocomposite catalysts, quintuple bonding and on-purpose olefin synthesis;Inorganic Chemistry in Germany;2023
4. Advances in Catalytic C–F Bond Activation and Transformation of Aromatic Fluorides;Catalysts;2022-12-18
5. Crystallographic Evidence of η1-Coordination of Bulky Aminopyridine in Halide-Containing Iron (II) Complexes;Crystals;2022-05-14
1.学者识别学者识别
2.学术分析学术分析
3.人才评估人才评估
"同舟云学术"是以全球学者为主线，采集、加工和组织学术论文而形成的新型学术文献查询和分析系统，可以对全球学者进行文献检索和人才价值评估。用户可以通过关注某些学科领域的顶尖人物而持续追踪该领域的学科进展和研究前沿。经过近期的数据扩容，当前同舟云学术共收录了国内外主流学术期刊6万余种，收集的期刊论文及会议论文总量共计约1.5亿篇，并以每天添加12000余篇中外论文的速度递增。我们也可以为用户提供个性化、定制化的学者数据。欢迎来电咨询！咨询电话：010-8811{复制后删除}0370
www.globalauthorid.com
TOP
Copyright © 2019-2024 北京同舟云网络信息技术有限公司 京公网安备11010802033243号 京ICP备18003416号-3