Rare-earth metal alkyl complexes bearing an alkoxy N-heterocyclic carbene ligand: synthesis, characterization, catalysis for isoprene polymerization
Author:
Affiliation:
1. State Key Laboratory of Polymer Physics and Chemistry
2. Changchun Institute of Applied Chemistry
3. Chinese Academy of Sciences
4. Changchun 130022
5. People's Republic of China
Abstract
The new rare-earth metal alkyl complexes bearing alkoxy NHC ligands were prepared, which showed moderate cis-1,4 selectivity for isoprene polymerization.
Publisher
Royal Society of Chemistry (RSC)
Subject
Materials Chemistry,General Chemistry,Catalysis
Link
http://pubs.rsc.org/en/content/articlepdf/2015/NJ/C5NJ00737B
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1. The Development of L2X2RuCHR Olefin Metathesis Catalysts: An Organometallic Success Story
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4. Direct β-Activation of Saturated Aldehydes to Formal Michael Acceptors through Oxidative NHC Catalysis
5. Ni(NHC)]-Catalyzed Cycloaddition of Diynes and Tropone: Apparent Enone Cycloaddition Involving an 8π Insertion
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