Weak interactions cause selective cocrystal formation of lanthanide nitrates and tetra-2-pyridinylpyrazine
Author:
Affiliation:
1. Beijing National Laboratory for Molecular Sciences (BNLMS)
2. CAS Key Laboratory of Photochemistry
3. State Key Laboratory for Structural Chemistry of Unstable and Stable Species
4. Institute of Chemistry
5. Chinese Academy of Sciences
Abstract
Two series of cocrystals Ln(NO3)5·H2TPPZ are synthesized enlightening the lanthanide contraction effect and weak hydrogen bonding interactions in determining the selective cocrystallization, stability and energy transfer for luminescence.
Funder
CAS
Publisher
Royal Society of Chemistry (RSC)
Subject
Condensed Matter Physics,General Materials Science,General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2018/CE/C7CE02098H
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