Synthesis, crystal structure, solid-state optical property and C–H activation of sp3 carbon of highly-stable 1-(2′,6′-dimesitylphenyl)-2,3,4,5-tetraphenylborole-Reference-Cited by-同舟云学术

Synthesis, crystal structure, solid-state optical property and C–H activation of sp3 carbon of highly-stable 1-(2′,6′-dimesitylphenyl)-2,3,4,5-tetraphenylborole

Published:2021 Issue:48 Volume:45 Page:22569-22573
ISSN:1144-0546
Container-title:New Journal of Chemistry
language:en
Short-container-title:New J. Chem.

Author:

Himeno Ryoji¹,Ito Shunichiro¹^ORCID,Tanaka Kazuo¹^ORCID,Chujo Yoshiki¹

Affiliation:

1. Department of Polymer Chemistry, Graduate School of Engineering, Kyoto University Katsura, Nishikyo-ku, Kyoto 615-8510, Japan

Abstract

We synthesized a borole having near-infrared absorption and found transformation to the unexpected fused molecule through C–H activation.

Funder

Japan Society for the Promotion of Science

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2021/NJ/D1NJ04666G

Reference42 articles.

1. Synthesis and Structures of a Series of Bulky “Rind-Br” Based on a Rigid Fused-Rings-Hydrindacene Skeleton

2. Synthesis and Optical Properties of Stable Gallafluorene Derivatives: Investigation of Their Emission via Triplet States

3. Electron‐Deficient Conjugated Materials via p–π* Conjugation with Boron: Extending Monomers to Oligomers, Macrocycles, and Polymers

4. Enhancing the Acceptor Character of Conjugated Organoborane Macrocycles: A Highly Electron‐Deficient Hexaboracyclophane

5. Extended conjugated borenium dimers via late stage functionalization of air-stable borepinium ions

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