A bis(diketopyrrolopyrrole) dimer-containing ligand in platinum(ii) polyyne oligomers exhibiting ultrafast photoinduced electron transfer with PCBM and solar cell properties

Author:

Nos Mélodie12345,Marineau-Plante Gabriel6789,Gao Di12345,Durandetti Muriel11011412ORCID,Hardouin Julie11011413ORCID,Karsenti Paul-Ludovic6789,Gupta Gaurav14151617ORCID,Sharma Ganesh D.14151617ORCID,Harvey Pierre D.6789ORCID,Lemouchi Cyprien12345ORCID,Le Pluart Loïc12345

Affiliation:

1. Normandie Univ.

2. ENSICAEN

3. UNICAEN

4. CNRS

5. LCMT

6. Département de chimie

7. Université de Sherbrooke

8. Sherbrooke

9. Canada

10. UNIROUEN

11. INSA Rouen

12. COBRA

13. PBS

14. Department of Physics

15. LNM Institute of Information Technology (Deemed to be University)

16. 302017 Jaipur

17. India

Abstract

We report the synthesis and characterization of a bis(diketopyrrolopyrrole) dimer-containing ligand in platinum(ii) polyyne oligomer P4 with very good photovoltaic performance, PCE = 9.54% (P4; Jsc = 16.24 mA cm−2, Voc = 0.89 V, FF = 0.66).

Funder

Natural Sciences and Engineering Research Council of Canada

Department of Science and Technology, Ministry of Science and Technology

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry

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