Suppressing Ge-vacancies to achieve high single-leg efficiency in GeTe with an ultra-high room temperature power factor

Author:

Jia Ning12,Cao Jing3,Tan Xian Yi32ORCID,Zheng Jie3ORCID,Chien Sheau Wei3,Yang Le34,Chen Kewei5,Ng Hong Kuan3,Faye Duran Solco Samantha3ORCID,Liu Hongfei3,Ivan Tan Chee Kiang3,Li Zibiao34ORCID,Xu Jianwei3,Wu Jing3,Yan Qingyu2ORCID,Suwardi Ady34ORCID

Affiliation:

1. State Key Laboratory of Crystal Materials, Shandong University, Jinan 250100, China

2. School of Materials Science and Engineering, Nanyang Technological University, 639798, Singapore

3. Institute of Materials Research and Engineering, Agency for Science, Technology and Research, #08-03, 2 Fusionopolis Way, 138634, Singapore

4. Department of Materials Science and Engineering, National University of Singapore, 117575, Singapore

5. School of Mechanical and Aerospace Engineering, Nanyang Technological University, 639798, Singapore

Abstract

Adding Cu2Te, In, and Bi into GeTe results in an ultra-high power factor and average zT. A power conversion efficiency of 11.8% can be achieved in lead-free, single-leg GeTe between 323 and 745 K.

Funder

Science and Engineering Research Council

Ministry of Education – Singapore

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Renewable Energy, Sustainability and the Environment,General Chemistry

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