Ring expansion of unsubstituted aziridinium ylides to trifluoromethylated dehydropiperidines-Reference-Cited by-同舟云学术

Ring expansion of unsubstituted aziridinium ylides to trifluoromethylated dehydropiperidines

Published:2024 Issue:12 Volume:11 Page:3358-3363
ISSN:2052-4129
Container-title:Organic Chemistry Frontiers
language:en
Short-container-title:Org. Chem. Front.

Author:

Tang Jiaqi¹,Tian Tian¹,Wang Yingyu¹,Wei Dandan¹,Yang Yong¹,Wang Xinyu¹,Sivaguru Paramasivam¹^ORCID,Ning Yongquan¹^ORCID,Liu Zhaohong¹^ORCID,Nenajdenko Valentine²^ORCID

Affiliation:

1. Jilin Province Key Laboratory of Organic Functional Molecular Design & Synthesis, Department of Chemistry, Northeast Normal University, Changchun 130024, China

2. Department of Chemistry, Lomonosov Moscow State University, 119899 Moscow, Russia

Abstract

The first rhodium-catalyzed [3 + 3] ring expansion of unsubstituted aziridines was achieved using trifluoroalkenyl N-triftosylhydrazones as vinylcarbene precursors to afford a series of structurally diverse 2-trifluoromethylated dehydropiperidines under mild conditions.

Funder

National Natural Science Foundation of China

Higher Education Discipline Innovation Project

Fundamental Research Funds for the Central Universities

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/QO/D4QO00537F

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