Systematic radical species control by electron push–pull substitution in the perylene-based D–π

Systematic radical species control by electron push–pull substitution in the perylene-based D–π–A compounds

Published:2023 Issue:4 Volume:13 Page:2283-2293
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Ahn Mina¹,Lee Soyoon¹,Kim Min-Ji¹,Chae Minjung¹,Cho Dae Won²,Wee Kyung-Ryang¹^ORCID

Affiliation:

1. Department of Chemistry and Institute of Natural Science, Daegu University, Gyeongsan 38453, Republic of Korea

2. Department of Chemistry, Yeungnam University, Gyeongsan, Gyeongbuk 38541, Republic of Korea

Abstract

(D–π–A)˙−& (D–π–A)˙+are generated in response to electrical stimulation. Unlike (D–π–A)˙−, (D–π–A)˙+shows a systematically controllable substituent effect by the DPA R group ranging from electron-withdrawing F to electron-donating OMe group.

Funder

National Research Foundation of Korea

Ministry of Education

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/RA/D2RA06460J

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