Hydrophilic sulfonated bis-1,2,4-triazine ligands are highly effective reagents for separating actinides(iii) from lanthanides(iii) via selective formation of aqueous actinide complexes

Author:

Lewis Frank W.12345,Harwood Laurence M.1234,Hudson Michael J.1234,Geist Andreas678,Kozhevnikov Valery N.5910114,Distler Petr12131415,John Jan12131415

Affiliation:

1. Department of Chemistry

2. The University of Reading

3. Whiteknights

4. UK

5. Department of Applied Sciences

6. Karlsruher Institut für Technologie (KIT-INE)

7. Institut für Nukleare Entsorgung

8. Germany

9. Faculty of Health and Life Sciences

10. Northumbria University

11. Newcastle upon Tyne NE1 8ST

12. Department of Nuclear Chemistry

13. Czech Technical University in Prague

14. 115 19 Prague 1

15. Czech Republic

Abstract

Tetrasulfonated bis-1,2,4-triazine ligands can selectively complex and separate actinides from lanthanides in aqueous nitric acid with very high selectivities.

Funder

Ministry of Education, Youth and Sports

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Reference102 articles.

1. B. J. Mincher , Nuclear Energy and the Environment, ed. C. M. Wai and B. J. Mincher, ACS Symposium Series, ACS, Washington DC, 2010, vol. 1046, ch. 1, pp. 3–10

2. Nuclear Fission, The Energy Research Partnership Technology Report, The Energy Research Partnership, London, 2010, www.energyresearchpartnership.org.uk

3. Fuel Cycle Stewardship in a Nuclear Renaissance, The Royal Society Science Policy Centre Report 10/11, The Royal Society, London, 2011 (ISBN: 978-0-85403-891-6)

4. Chemistty of the Purex Process

5. Chemistry of nuclear fuel reprocessing: Current status

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