Selective halide ion binding templation effect for a quadruple-stranded-helicate enabling the activation of C

Selective halide ion binding templation effect for a quadruple-stranded-helicate enabling the activation of C–Br bonds

Published:2024 Issue: Volume: Page:
ISSN:2052-4129
Container-title:Organic Chemistry Frontiers
language:en
Short-container-title:Org. Chem. Front.

Author:

Fu Lei¹,Liu Yang¹,Jiang Zhiyuan²,Zhang Zhe¹^ORCID,Bai Qixia¹,Li Yu-Qing³,Chen Zhi⁴^ORCID,Li Xiaopeng⁴^ORCID,Wang Pingshan¹³^ORCID,Wu Tun¹

Affiliation:

1. Institute of Environmental Research at Greater Bay Area, Key Laboratory for Water Quality and Conservation of the Pearl River Delta, Ministry of Education, Guangzhou University, Guangzhou 510006, China

2. Department of Chemistry, The University of Hong Kong, Hong Kong SAR 999077, China

3. Hunan Key Laboratory of Micro & Nano Materials Interface Science; College of Chemistry and Chemical Engineering, Central South University Changsha 410083, China

4. College of Chemistry and Environmental Engineering, Shenzhen University, Shenzhen, Guangdong 518060, People's Republic of China

Abstract

Here, we report the study on mechanism of anion-induced templation effect, in which nucleophilic anions serving as ligand competitors to destroy partial coordination bonds in a library of metallo-macrocycles and form quadruple-stranded helicates.

Funder

National Natural Science Foundation of China

Basic and Applied Basic Research Foundation of Guangdong Province

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/QO/D4QO01373E

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