Bis-phenylethynyl polyhedral oligomeric silsesquioxanes: new high-temperature, processable thermosetting materials

Author:

Moore Levi M. J.1234ORCID,Zavala Jacob J.534,Lamb Jason T.534,Reams Josiah T.534,Yandek Gregory R.1234,Guenthner Andrew J.12346,Haddad Timothy S.534,Ghiassi Kamran B.1234ORCID

Affiliation:

1. Air Force Research Laboratory

2. Aerospace Systems Directorate

3. Edwards AFB

4. USA

5. ERC Incorporated

6. Nano Hydrophobics, Inc.

Abstract

After thermal crosslinking, bis-phenylethynyl POSS exhibits 5% mass loss temperatures approaching 600 °C, the highest of reported POSS compounds.

Funder

Air Force Office of Scientific Research

U.S. Department of Energy

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Reference25 articles.

1. I.Hamerton and L.Mooring , The Use of Thermosets in Aerospace Applications , in Thermosets , ed. Q. Guo , Woodhead Publishing , 2012 , pp. 189–227

2. National Research Council , Structural and Multifunctional Materials , in Materials Research to Meet 21st-Century Defense Needs , The National Academies Press , Washington, DC , 2003 , pp. 27–54

3. Recent developments in the chemistry of cyanate esters

4. Silicon-containing trifunctional and tetrafunctional cyanate esters: Synthesis, cure kinetics, and network properties

5. Polybenzoxazine alloys and blends: Some unique properties and applications

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