Shining light on halogen-bonding complexes: a catalyst-free activation mode of carbon–halogen bonds for the generation of carbon-centered radicals-Reference-Cited by-同舟云学术

Shining light on halogen-bonding complexes: a catalyst-free activation mode of carbon–halogen bonds for the generation of carbon-centered radicals

Published:2023 Issue:21 Volume:14 Page:5545-5568
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Piedra Helena F.¹^ORCID,Valdés Carlos¹^ORCID,Plaza Manuel¹^ORCID

Affiliation:

1. Departamento de Química Orgánica e Inorgánica, Instituto Universitario de Química Organometálica “Enrique Moles” and Centro de Innovación en Química Avanzada (ORFEO-CINQA), Universidad de Oviedo, Julián Clavería 8, 33006 Oviedo, Spain

Abstract

This review provides a comprehensive overview on examples of how photochemical excitation of halogen-bonding complexes can be useful for the generation of carbon-centered radicals and their participation in synthetic organic transformations.

Funder

Fundación para el Fomento en Asturias de la Investigación Científica Aplicada y la Tecnología

Agencia Estatal de Investigación

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/SC/D3SC01724A

Reference94 articles.

1. Forging C(sp3)–C(sp3) Bonds with Carbon-Centered Radicals in the Synthesis of Complex Molecules

2. Generation of Alkyl Radicals: From the Tyranny of Tin to the Photon Democracy