Capture and detection of SO<sub>2</sub> using a chemically stable Mg(<scp>ii</scp>)

Capture and detection of SO₂ using a chemically stable Mg(ii)–MOF

Published:2022 Issue:36 Volume:10 Page:18636-18643
ISSN:2050-7488
Container-title:Journal of Materials Chemistry A
language:en
Short-container-title:J. Mater. Chem. A

Author:

Martínez-Ahumada Eva¹,Kim Dae won²,Wahiduzzaman Mohammad³,Carmona-Monroy Paulina¹,López-Olvera Alfredo¹,Williams Daryl R.⁴,Martis Vladimir⁵,Lara-García Hugo A.⁶,López-Morales S.⁷,Solis-Ibarra Diego¹^ORCID,Maurin Guillaume³^ORCID,Ibarra Ilich A.¹^ORCID,Hong Chang Seop²^ORCID

Affiliation:

1. Laboratorio de Fisicoquímica y Reactividad de Superficies (LaFReS), Instituto de Investigaciones en Materiales, Universidad Nacional Autónoma de México, Circuito Exterior s/n, CU, Del. Coyoacán, 04510, Ciudad de México, Mexico

2. Department of Chemistry, Korea University, Seoul 02841, Republic of Korea

3. ICGM, Univ. Montpellier, CNRS, ENSCM, Montpellier, 34293, France

4. Director of Discovery Space and Professor of Particle Science, Department of Chemical Engineering, Imperial College, Kensington, London SW7 2BY, UK

5. Surface Measurement Systems, Unit 5, Wharfside, Rosemont Road, London HA0 4PE, UK

6. Instituto de Física, Universidad Nacional Autónoma de México, Circuito de la Investigación Científica s/n, CU, Coyoacán, Ciudad de México, Mexico

7. Instituto de Investigaciones en Materiales, Universidad Nacional Autónoma de México, Circuito Exterior s/n, CU, Del. Coyoacán, Ciudad de México, Mexico

Abstract

Mg2(dobpdc) was confirmed to be an optimal adsorbent for SO2 capture showing high uptake and chemical stability to dry and humid SO2. Advanced molecular simulations have been coupled to determine the molecular mechanisms responsible for high SO2 adsorption.

Funder

National Research Foundation of Korea

Consejo Nacional de Ciencia y Tecnología

Universidad Nacional Autónoma de México

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Renewable Energy, Sustainability and the Environment,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/TA/D2TA04842F

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