Spin crossover in Hofmann-like coordination polymers. Effect of the axial ligand substituent and its position-Reference-Cited by-同舟云学术

Spin crossover in Hofmann-like coordination polymers. Effect of the axial ligand substituent and its position

Published:2023 Issue:22 Volume:47 Page:10781-10795
ISSN:1144-0546
Container-title:New Journal of Chemistry
language:en
Short-container-title:New J. Chem.

Author:

Avila Y.¹^ORCID,Pérez O.¹^ORCID,Sánchez L.¹^ORCID,Vázquez M. C.¹^ORCID,Mojica R.¹^ORCID,González M.¹^ORCID,Ávila M.¹^ORCID,Rodríguez-Hernández J.²^ORCID,Reguera E.¹^ORCID

Affiliation:

1. National Polytechnic Institute, Center for Applied Science and Advanced Technology, Legaria Unit, Mexico City, Mexico

2. Center for Applied Research in Chemistry (CIQA), Saltillo, Coahuila, Mexico

Abstract

Thermally induced spin crossover in the Fe(3-hydroxypyridine)2[M(CN)4] series with M = Ni, Pd, and Pt is reported. The role of the distortion of the iron atom coordination environment in the possibility of observing the spin crossover is explored.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2023/NJ/D3NJ01498C

Reference88 articles.

1. The nature of spin-state transitions in solid complexes of iron(II) and the interpretation of some associated phenomena

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