Selective signalling of alcohols by a molecular lattice and mechanism of single-crystal-to-single-crystal transformations

Author:

Costa José Sánchez1234ORCID,Rodríguez-Jiménez Santiago1234ORCID,Craig Gavin A.1234ORCID,Barth Benjamin1234,Beavers Christine M.5678ORCID,Teat Simon J.5678ORCID,Gagnon Kevin J.5678,Barrios Leoní A.12349ORCID,Roubeau Olivier1011124ORCID,Aromí Guillem12349ORCID

Affiliation:

1. Departament de Química Inorgànica i Orgànica

2. Universitat de Barcelona

3. 08028 Barcelona

4. Spain

5. Advanced Light Source

6. Berkeley Laboratory

7. Berkeley

8. USA

9. Institute of Nanoscience and Nanotechnology of the University of Barcelona (IN2UB)

10. Instituto de Ciencia de Materiales de Aragón (ICMA)

11. CSIC and Universidad de Zaragoza

12. Zaragoza

Abstract

A molecular material undergoes spin-switching as it exchanges MeOH, EtOH or nPrOH with acetone from the lattice. The subsequent thermal single-crystal-to-single-crystal desorption of nPrOH is followed by single crystal X-ray diffraction snapshots.

Funder

Secretaría de Estado de Investigación, Desarrollo e Innovación

Fundación Agencia Aragonesa para la Investigación y el Desarrollo

Institució Catalana de Recerca i Estudis Avançats

Lawrence Berkeley National Laboratory

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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