Synthesis, oligomerization and catalytic studies of a redox-active Ni4-cubane: a detailed mechanistic investigation-Reference-Cited by-同舟云学术

Synthesis, oligomerization and catalytic studies of a redox-active Ni4-cubane: a detailed mechanistic investigation

Published:2021 Issue:37 Volume:11 Page:22849-22858
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Kushvaha Saroj Kumar¹²³⁴,Francis Maria¹⁵⁶⁴^ORCID,Kumar Jayasree¹²³⁴,Nag Ekta¹⁵⁶⁴,Ravichandran Prathap¹²³⁴,Roy Sudipta¹⁵⁶⁴^ORCID,Chandra Mondal Kartik¹²³⁴^ORCID

Affiliation:

1. Department of Chemistry

2. Indian Institute of Technology Madras

3. Chennai 600036

4. India

5. Indian Institute of Science Education and Research (IISER)

6. Tirupati 517507

Abstract

A robust tetrameric nickel complex [Ni₄((O_al⁻)₂L-Me)₄(s)₄] (s = solvent) with cubane-like Ni₄O₄ core topology identified as the efficient catalyst for the diastereoselective cyclopropanation of aromatic heterocycles.

Funder

Science and Engineering Research Board

Indian Institute of Technology Madras

Council of Scientific and Industrial Research, India

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/RA/D1RA03071J

Reference41 articles.

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3. Four- and five-coordinate nickel(II) complexes of the flexible triphosphine bis(2-diphenylphosphinoethyl)phenylphosphine

4. New nickel(II)-copper(II) heterodinuclear complexes with hexa- and pentacoordinated nickel(II) ions. Magnetostructural correlations

5. Nickel Complexes Bearing 2‐(Benzimidazol‐2‐yl)‐1,10‐phenanthrolines: Synthesis, Characterization and Their Catalytic Behavior Toward Ethylene Oligomerization

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