Iodine-catalysed sp3 C–H sulfonylation to form β-dicarbonyl sulfones with sodium sulfinates

Author:

Gao Wen-Chao123,Zhao Jin-Jin123,Chang Hong-Hong123,Li Xing123,Liu Qiang123,Wei Wen-Long123

Affiliation:

1. College of Chemistry and Chemical Engineering

2. Taiyuan University of Technology

3. Taiyuan, P. R. China

Abstract

I2 catalysed sp3 C–H sulfonylation to synthesize β-dicarbonyl sulfones with sodium sulfinate as the sulfonyl source.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Reference23 articles.

1. N. S. Simpkins , Sulfones in organic synthesis, in Tetrahedron Organic Chemistry Series, ed. J. E. Baldwin and P. D Margnus, Pergamon Press, Oxford, 1993, vol. 10

2. K. Shanak , Synthesis of Sulfones, Sulfoxides and Cyclic Sulfides, ed. S. Patai and Z. Rappoprt, Wiley, Chichester, 1994

3. Sulfonyl: a new application of electron-withdrawing substituent in highly efficient photovoltaic polymer

4. Silica Sulfuric Acid as a Mild and Efficient Reagent for the Synthesis of 1,4-Diazepine and 1,5-Benzodiazepine Derivatives

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