The Ireland–Claisen rearrangement as a probe for the diastereoselectivity of nucleophilic attack on a double bond adjacent to a stereogenic centre carrying a silyl group-Reference-Cited by-同舟云学术

The Ireland–Claisen rearrangement as a probe for the diastereoselectivity of nucleophilic attack on a double bond adjacent to a stereogenic centre carrying a silyl group

Published:2003 Issue:22 Volume:1 Page:4005-4016
ISSN:1477-0520
Container-title:Org. Biomol. Chem.
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Betson Mark S.,Fleming Ian

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2003/OB/B305881F

Reference40 articles.

1. The diastereoselectivity of electrophilic attack on trigonal carbon adjacent to a stereogenic centre: diastereoselective alkylation and protonation of open-chain enolates having a stereogenic centre carrying a silyl group at the ? position

2. The diastereoselectivity of electrophilic attack on trigonal carbon adjacent to a stereogenic centre: diastereoselective aldol reactions of open-chain enolates having a stereogenic centre carrying a silyl group at the ? position

3. The regiochemistry and stereochemistry of the hydroboration of allylsilanes

4. Accurate determination of the extent to which an SE2′ reaction of an allylsilane is anti

5. Accurate determination of the extent to which the SE2′ reactions of an allenylsilane are stereospecifically anti

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