Electroreductive deuteroarylation of alkenes enabled by an organo-mediator-Reference-Cited by-同舟云学术

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Electroreductive deuteroarylation of alkenes enabled by an organo-mediator

Published:2024 Issue:29 Volume:15 Page:11418-11427
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Li Xinling¹,Zhou Jianfeng¹,Deng Weijie¹,Wang Ziliang¹,Wen Yating¹,Li Zhenjie¹,Qiu Youai²^ORCID,Huang Yubing¹^ORCID

Affiliation:

1. School of Environmental and Chemical Engineering, Wuyi University, Jiangmen, 529090, P. R. China

2. State Key Laboratory and Institute of Elemento-Organic Chemistry, Frontiers Science Center for New Organic Matter, College of Chemistry, Nankai University, 94 Weijin Road, Tianjin, 300071, People's Republic of China

Abstract

An environmentally friendly electroreduction approach is disclosed for site-specific introduction of deuterium via anti-Markovnikov selective deuteroarylation of alkenes and aryl iodides with bipyridine as a mediator and D2O as a ‘D’ source.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/SC/D4SC03049D

Reference69 articles.

1. The Deuterium Isotope Effect

2. Applications of Deuterium in Medicinal Chemistry

3. Catalytic α-Selective Deuteration of Styrene Derivatives

4. Dehalogenative Deuteration of Unactivated Alkyl Halides Using D2O as the Deuterium Source

5. Efficient Access to Deuterated and Tritiated Nucleobase Pharmaceuticals and Oligonucleotides using Hydrogen‐Isotope Exchange

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