Depolymerization of polystyrene under ambient conditions
Author:
Affiliation:
1. Ames Laboratory US DOE
2. 311 Iowa State University
3. Ames
4. USA
5. Department of Chemistry
6. Department of Materials Science and Engineering
7. Clemson University
8. 161 Sirrine Hall
9. 515 Calhoun Drive
10. Clemson
Abstract
Ball milling of polystyrene under ambient conditions in metal containing vials causes scission of macromolecules, resulting in partial dismantling to styrene. Reactions proceeds via intermediate carbon-based free radicals that are detectable by EPR.
Funder
Basic Energy Sciences
Ames Laboratory
Iowa State University
National Science Foundation
Office of Experimental Program to Stimulate Competitive Research
Publisher
Royal Society of Chemistry (RSC)
Subject
Materials Chemistry,General Chemistry,Catalysis
Link
http://pubs.rsc.org/en/content/articlepdf/2021/NJ/D0NJ05984F
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