The lone-pair-electron-driven phase transition and order–disorder processes in thermochromic (2-MIm)SbI4 organic–inorganic hybrid-Reference-Cited by-同舟云学术

The lone-pair-electron-driven phase transition and order–disorder processes in thermochromic (2-MIm)SbI4 organic–inorganic hybrid

Published:2017 Issue:47 Volume:46 Page:16605-16614
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Gągor A.¹²³^ORCID,Banach G.⁴⁵⁶³,Węcławik M.⁷⁸⁹³,Piecha-Bisiorek A.⁷⁸⁹³^ORCID,Jakubas R.⁷⁸⁹³^ORCID

Affiliation:

1. W. Trzebiatowski Institute of Low Temperature and Structure Research PAS

2. 50-950 Wrocław

3. Poland

4. Institute of Physics

5. University of Zielona Góra

6. 65-516 Zielona Góra

7. Faculty of Chemistry

8. University of Wrocław

9. 50-383 Wrocław

Abstract

Thermochromic (2-MIm)SbI₄ hybrid crystals undergo normal to modulated phase transition at 295 K which affects mainly the anionic substructure. Pronounced color changes correlate to modifications of the intra chain Sb–I and Sb⋯Sb connections.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2017/DT/C7DT03622A

Reference39 articles.

1. The Templating Effect and Photochemistry of Viologens in Halometalate Hybrid Crystals

2. Polynuclear halide complexes of Bi(III): From structural diversity to the new properties

3. Metal–organic complex ferroelectrics

4. Ferroelectric Metal–Organic Frameworks

5. Improved Photochromic Properties on Viologen-Based Inorganic–Organic Hybrids by Using π-Conjugated Substituents as Electron Donors and Stabilizers

Cited by 20 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Polymorphism and Red Photoluminescence Emission from 5s2 Electron Pairs of Sb(III) in a New One-Dimensional Organic–Inorganic Hybrid Based on Methylhydrazine: MHy2SbI5;Molecules;2024-01-17

2. Structural Study, Spectroscopic Characterization and Evaluation of the Antimicrobial Behavior of a New Fe (III) Organic‐Inorganic Hybrid Material: (C₈H₁₄N₂)₄[(FeCl₆)(FeCl₄)]Cl₄;ChemistrySelect;2023-09-07

3. Supramolecular structures of new tetranuclear hydroxypiperidine iodoantimonates(iii);Russian Chemical Bulletin;2023-03

4. New lead-free hybrid halometallates with dioctahedral anions synthesized using the template function of homopiperazine;Russian Chemical Bulletin;2023-01

5. Synthesis, crystal structure, optical, thermal and magnetic studies of a new organic-inorganic hybrid based on tetrachloroferrate (III);Journal of Solid State Chemistry;2021-11