Direct synthesis of β-acyloxy aldehydes from linear allylic esters using O2 as the sole oxidant-Reference-Cited by-同舟云学术

Direct synthesis of β-acyloxy aldehydes from linear allylic esters using O2 as the sole oxidant

Published:2022 Issue:3 Volume:9 Page:687-692
ISSN:2052-4129
Container-title:Organic Chemistry Frontiers
language:en
Short-container-title:Org. Chem. Front.

Author:

Lei Shu-Hui¹,Zhong Ya¹,Cai Xian-Peng¹,Huang Qing¹,Qu Jian-Ping¹^ORCID,Kang Yan-Biao²^ORCID

Affiliation:

1. Institute of Advanced Synthesis, School of Chemistry and Molecular Engineering, Nanjing Tech University, Nanjing 211816, China

2. Hefei National Laboratory for Physical Sciences at the Microscale, School of Chemistry and Materials Science, University of Science and Technology of China, Hefei 230026, China

Abstract

A simple and practical preparation of β-O substituted aldehydes directly from linear allylic esters using oxygen as the sole oxidant and tert-butyl nitrite as a simple and sole redox cocatalyst is developed.

Funder

National Key Research and Development Program of China

National Natural Science Foundation of China

Nanjing Tech University

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/QO/D1QO01607E

Reference28 articles.

1. Katalytische Umsetzungen von Olefinen an Platinmetall-Verbindungen Das Consortium-Verfahren zur Herstellung von Acetaldehyd