Economical synthesis of cyclic carbonates from carbon dioxide and halohydrins using K2CO3

Author:

Hirose Takuji1234,Shimizu Shinsuke1234,Qu Shujie1234,Shitara Hiroaki1234,Kodama Koichi1234,Wang Lin1234

Affiliation:

1. School of Science and Engineering

2. Saitama University

3. Saitama 338-8570

4. Japan

Abstract

Highly simple, economical and selective synthesis of five-membered cyclic carbonates was presented as a reaction of CO2 and various 1,2-halohydrins using K2CO3 at 1 atm of CO2 and 30 °C in DMF.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Reference44 articles.

1. CO2 Chemistry, in Advances in Inorganic Chemistry, ed. M. Aresta and R. van Eldik, Academic Press, San Diego, 2014, vol. 66

2. Transformation and Utilization of Carbon Dioxide, in Green Chemistry and Sustainable Technology, ed. B. M. Bhanage, and M. Araki, Springer, Heidelberg, 2014

3. Green Carbon Science: Scientific Basis for Integrating Carbon Resource Processing, Utilization, and Recycling

4. Transformation of Carbon Dioxide

5. The synthesis of organic carbonates from carbon dioxide

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