Zinc hydridotriphenylborates supported by a neutral macrocyclic polyamine
Author:
Affiliation:
1. Institute of Inorganic Chemistry
2. RWTH Aachen University
3. 52056 Aachen
4. Germany
Abstract
A neutral macrocyclic polyamine 1,4,7,10-tetramethyl-1,4,7,10-tetraazacyclododecane (Me4TACD) stabilizes cationic zinc hydridotriphenylborates that react with CO2(1 atm) under insertion into the B–H bonds.
Funder
Deutsche Forschungsgemeinschaft
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2017/DT/C7DT01094J
Reference36 articles.
1. (Pyridine)(tetrahydroborato)zinc Complex, [Zn(BH4)2(py)], as a New Stable, Efficient and Chemoselective Reducing Agent for Reduction of Carbonyl Compounds
2. Use of zinc borohydride as an efficient and highly selective reducing agent. Selective reduction of ketones and conjugated aldehydes over conjugated enones
3. Structure and decomposition of zinc borohydride ammonia adduct: towards a pure hydrogen release
4. Ammine bimetallic (Na, Zn) borohydride for advanced chemical hydrogen storage
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