Accessing the triplet state of perylenediimide by radical-enhanced intersystem crossing-Reference-Cited by-同舟云学术

Accessing the triplet state of perylenediimide by radical-enhanced intersystem crossing

Published:2022 Issue:22 Volume:13 Page:6732-6743
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Mayländer Maximilian¹^ORCID,Nolden Oliver²^ORCID,Franz Michael¹^ORCID,Chen Su³^ORCID,Bancroft Laura³^ORCID,Qiu Yunfan³,Wasielewski Michael R.³^ORCID,Gilch Peter²^ORCID,Richert Sabine¹^ORCID

Affiliation:

1. Institute of Physical Chemistry, University of Freiburg, Albertstraße 21, 79104 Freiburg, Germany

2. Institute of Physical Chemistry, Heinrich Heine University Düsseldorf, Universitätsstraße 1, 40225 Düsseldorf, Germany

3. Department of Chemistry, Center for Molecular Quantum Transduction, Institute for Sustainability and Energy at Northwestern, Northwestern University, 2145 Sheridan Road, Evanston, IL 60208-3113, USA

Abstract

The triplet state of PDI can be sensitized efficiently by radical-enhanced intersystem crossing. A detailed study of several related structures allows us to propose new strategies to optimize triplet formation in materials for optoelectronic devices.

Funder

Deutsche Forschungsgemeinschaft

U.S. Department of Energy

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/SC/D2SC01899C

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1. Quintet multiexciton dynamics in singlet fission

2. Strongly exchange-coupled triplet pairs in an organic semiconductor