Can a highly flexible copper(i) cluster-containing 1D and 2D coordination polymers exhibit MOF-like properties?-Reference-Cited by-同舟云学术

Can a highly flexible copper(i) cluster-containing 1D and 2D coordination polymers exhibit MOF-like properties?

Published:2016 Issue:28 Volume:45 Page:11413-11421
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Bonnot Antoine¹²³⁴,Juvenal Frank¹²³⁴,Lapprand Anthony⁵⁶⁷⁸,Fortin Daniel¹²³⁴,Knorr Michael⁵⁶⁷⁸,Harvey Pierre D.¹²³⁴

Affiliation:

1. Département de Chimie

2. Université de Sherbrooke

3. Sherbrooke

4. Canada J1 K 2R1

5. Institut UTINAM UMR CNRS 6213

6. Université de Franche-Comté

7. 25030 Besançon

8. France

Abstract

The p-TolS(CH₂)₈STol-p and p-tBuC₆H₄S(CH₂)₈SC₆H₄-tBu-p ligands react with CuI respectively in MeCN and EtCN and in EtCN form the 2D and 1D polymers [Cu₈I₈(p-TolS(CH₂)₈STol-p)₃(solvent)₂]_n (solvent = MeCN, EtCN) and [Cu₄I₄(p-tBuC₆H₄S(CH₂)₈SC₆H₄-tBu-p)₂(EtCN)]_n susceptible to exchange solvent molecules.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/DT/C6DT01375A

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