Oxidation of uranium(iv) thiocyanate complexes: cation–cation interactions in mixed-valent uranium coordination chains-Reference-Cited by-同舟云学术

Oxidation of uranium(iv) thiocyanate complexes: cation–cation interactions in mixed-valent uranium coordination chains

Published:2019 Issue:20 Volume:48 Page:6704-6708
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Nuzzo Stefano¹²³⁴⁵,van Leusen Jan⁶⁷⁸⁹^ORCID,Twamley Brendan¹²³⁴⁵,Platts James A.¹¹⁰¹¹¹²,Kögerler Paul⁶⁷⁸⁹^ORCID,Baker Robert J.¹²³⁴⁵^ORCID

Affiliation:

1. School of Chemistry

2. University of Dublin

3. Trinity College

4. Dublin 2

5. Ireland

6. Institute of Inorganic Chemistry

7. RWTH Aachen University

8. D-52074 Aachen

9. Germany

10. Cardiff University

11. Cardiff

12. UK

Abstract

Oxidation of Cs₄[U(NCS)₈] in different solvents results in two mixed-valent uranium compounds. Spectroscopic, magnetic and computational data support a unique [U^IVU^VU^IV][U^VI] oxidation state assignment in [U(DMF)₈(μ-O)U(NCS)₅(μ-O)U(DMF)₇(NCS)][UO₂(NCS)₅].

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/DT/C9DT01005J

Reference42 articles.

1. T. W. Hayton and N.Kaltsoyannis , Organometallic Actinide Complexes with Novel Oxidation States and Ligand Types , in Experimental and theoretical approaches to actinide chemistry: from fundamental systems to practical applications , ed. J. K. Gibson and W. A. de Jong , John Wiley & Sons Inc. , 2018

2. Organometallic Neptunium Chemistry

3. Thorium coordination: A comprehensive review based on coordination number

4. The Renaissance of Non-Aqueous Uranium Chemistry

5. Recent Developments in Synthesis and Structural Chemistry of Nonaqueous Actinide Complexes

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