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Escape of anions from geminate recombination in THF due to charge delocalization

  • Published:2017 Issue:48 Volume:19 Page:32272-32285
  • ISSN:1463-9076
  • Container-title:Physical Chemistry Chemical Physics
  • language:en
  • Short-container-title:Phys. Chem. Chem. Phys.

Author:

Chen Hung-Cheng1234,Cook Andrew R.1234ORCID,Asaoka Sadayuki5678,Boschen Jeffery S.910114,Windus Theresa L.910114,Miller John R.1234ORCID

Affiliation:

1. Chemistry Department

2. Brookhaven National Laboratory

3. Upton

4. USA

5. Faculty of Materials Science and Engineering

6. Kyoto Institute of Technology

7. Kyoto 606-8585

8. Japan

9. Department of Chemistry and Ames Laboratory (USDOE)

10. Iowa State University

11. Ames

Abstract

Geminate recombination of 24 radical anions (M˙−) with solvated protons (RH2+) was studied in tetrahydrofuran (THF) with pulse radiolysis.

Funder

Basic Energy Sciences

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

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