Oxidation and reduction processes of platinum nanoparticles observed at the atomic scale by environmental transmission electron microscopy
Author:
Affiliation:
1. The Institute of Scientific and Industrial Research
2. Osaka University
3. Ibaraki, Japan
4. Division of Materials and Manufacturing Science
5. Graduate School of Engineering
Abstract
Atomic layers of Pt oxides were gradually formed on the surface of Pt nanoparticles in O2 and the oxides were reduced to Pt promptly in both vacuum and gas including CO. H2O vapor suppressed the surface oxidation.
Publisher
Royal Society of Chemistry (RSC)
Subject
General Materials Science
Link
http://pubs.rsc.org/en/content/articlepdf/2014/NR/C4NR04352A
Reference34 articles.
1. Structure and Reactivity of Surface Oxides on Pt(110) during Catalytic CO Oxidation
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3. Density functional theory study of platinum oxides: From infinite crystals to nanoscopic particles
4. In Situ and Real-Time Monitoring of Oxide Growth in a Few Monolayers at Surfaces of Platinum Nanoparticles in Aqueous Media
5. In situ X-ray probing reveals fingerprints of surface platinum oxide
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