Relative effects of polymer composition and sample preparation on glass dynamics-Reference-Cited by-同舟云学术

Relative effects of polymer composition and sample preparation on glass dynamics

Published:2022 Issue:35 Volume:18 Page:6511-6516
ISSN:1744-683X
Container-title:Soft Matter
language:en
Short-container-title:Soft Matter

Author:

Elder Robert M.¹,Forster Amanda L.²,Krishnamurthy Ajay²,Dennis Joseph M.¹,Akiba Hiroshi³,Yamamuro Osamu³,Ito Kanae⁴,Evans Katherine M.⁵,Soles Christopher⁵,Sirk Timothy W.¹^ORCID

Affiliation:

1. Polymers Branch, U.S. DEVCOM Army Research Laboratory, Aberdeen Proving Ground, Maryland 21005, USA

2. Materials Measurement Science Division, National Institute of Standards and Technology, Gaithersburg, Maryland 20899, USA

3. Institute for Solid State Physics, University of Tokyo, Kashiwa, Chiba, 277-8581, Japan

4. Industrial Application Division, Spring-8, Japan Synchrotron Radiation Research Institute (JASRI), 1-1-1 Kouto, Sayo, Hyogo 679-5198, Japan

5. Materials Science and Engineering Division, National Institute of Standards and Technology, Gaithersburg, Maryland 20899, USA

Abstract

Size and geometry of free volume holes are related to cage dynamics in polymer glasses. Molecular simulations, positron annihilation spectroscopy and quasi-elastic neutron scattering show how the polarity of monomers and quench rate control the population of aspherical holes.

Funder

National Institute of Standards and Technology

Publisher

Royal Society of Chemistry (RSC)

Subject

Condensed Matter Physics,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/SM/D2SM00698G

Reference26 articles.

1. Nanovoid formation and mechanics: a comparison of poly(dicyclopentadiene) and epoxy networks from molecular dynamics simulations

2. Mechanics and nanovoid nucleation dynamics: effects of polar functionality in glassy polymer networks

3. Tenfold increase in the photostability of an azobenzene guest in vapor-deposited glass mixtures